I think airplay output to speakers is actually not possible.
Only Airplay input with connection of volumio as streaming server.
I have succesfully installed a forked-daapd daemon, working on standalone raspbian stretch with Zeppelin Air wireless connected
On QNAP NAS Music Station app I can see Zeppelin as Network player, but no sound is going out
If a part from this “iTunes” server can be implemented in Volumio, then the functionality would be present.
But it is only my wish and suggestion to volumio develpers